Solar expert, Michael Ginsberg, CEO of Mastering Green, talks about lead acid and lithium ion battery storage systems and the use of FLUKE 500 Series Solar/Renewable Energy/Management meters for maintaining them.
Battery storage plays a significant role in the future of renewable energy generation.
Lead-acid batteries start our cars and our generators. Solid workhorses, they are cheap and reliable, yet they do require a lot of maintenance.
One of the newest commercial battery types is lithium-ion. Lithium-ion batteries account for the largest share (59%) of operational installed capacity according to the International Renewable Energy Agency (IRENA) 2017 report, Electricity Storage and Renewables: Costs and Markets to 2030. They are lightweight, have a high energy density and can be fully depleted without issue. This is important with variable solar energy, which won’t always be able to charge the battery.
How to maintain batteries
Batteries are sensitive. They work best between 15 and 35 °C and require a charge controller to receive a specific amount of current. At low temperatures, the electrochemistry is slowed, and at high temperatures, internal corrosion is increased.
Often, a car will not start in cold temperatures: that’s because the battery cannot deliver as much current. In cold climates, a battery heater or thermal insulation may help, and in hot climates, batteries should be stored in shaded, well-ventilated spaces.
Another issue is terminal corrosion. This happens when hydrogen gas is released from the acid in the battery, reacting with other substances, or electrolyte leaking from overfilling with water or overcharging. To remove corrosion, an antioxidant material as recommended by the manufacturer should be used.
For lead-acid batteries, it is crucial to maintain a high state of charge (SOC). Lead-acid batteries have a low depth of discharge, meaning a small amount of their total capacity should be used. A too-low SOC can lead to sulphation, a build-up of small sulphate crystals on the terminals, which reduces performance. To handle sulphation on the terminals, the SOC n needs to be kept high, and if it gets too low, a desulphating battery charger can be used to dissolve the sulphates with high-frequency electronic pulses. Also, an alarm can be used with a visual and audible indication to alert a low battery state of charge – 50% for lead acid battery types.
How to diagnose battery health
Technicians need to know the internal health of a battery to maintain them. Here, the Fluke 500 Series Battery Analyser can be used by connecting the leads to the negative and positive terminals and turning the switch to milli-ohms (mΩ). The display will simultaneously read battery voltage and internal resistance. Low voltage indicates a low state of charge and high internal resistance means internal deterioration.
It is essential to test the battery in an open-circuit state – after 24 hours for lead-acid batteries. The Analyser corrects for temperature to ensure accuracy, saves up to 10 thresholds, and sends the readings to the Fluke Battery Management Software for viewing trends.
Capacity loss refers to the battery storing less charge. Technicians can determine the capacity loss using the Analyser in discharge mode, where the battery voltage is read multiple times until it drops below the cut-off voltage, which can cause damage.
A hydrometer, which measures the relative density of liquids, can also be used to measure electrolyte specific gravity, an indicator of a battery’s state of charge.
Evolution of energy storage technology
Although more expensive than lead-acid batteries, lithium-ion batteries represent a significant improvement in terms of maintenance. While regularly checks are needed, and their SOC should be kept as close to 25 °C as possible, they have higher energy density, making them lighter. They also have higher depth of discharge, meaning much of their charge can be depleted before recharging, which is great for variable solar and wind power.
Thermal runaway, in which overcharging, a short circuit, or high temperature creates a feedback loop that rapidly accelerates temperatures until explosion, is an issue. Using a cathode with a higher temperature tolerance, such as iron phosphate (FePO4), mitigates thermal runaway.
New battery technologies, such as saltwater and liquid metal batteries, which promise both low maintenance and cost, are coming on the market.
Importance of battery maintenance
The answer to whether batteries are worth it for your facility comes down to priorities and costs. Lead-acid batteries have low upfront costs but high ongoing maintenance costs, including weekly cleaning, testing, and top-up tasks. On the other hand, lithium-ion batteries have high upfront costs but low ongoing maintenance costs.
Regardless, as the costs of lithium-ion and other non-lead acid batteries decline and the adoption of solar and wind energy grows, batteries will become an increasingly essential part of a facility.
To watch a video about the use of Fluke Solar solutions, click here.
For more product information about the Fluke 500 Series Solar, click here.
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